13.3 Reactions of Ethers

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    Crown Ethers

    -Solvate various alkali metal ions

    crown ethers 01
    crown ethers 02

    Acidic Cleavage -- Reaction with H-X (HCl, HBr, or HI)

    -SN1 for 3° and 2° carbons; SN2 for 1° carbons

    acidic cleavage of ethers
    acidic cleavage of phenyl ether