19.1 How to Assign Oxidation Numbers

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Oxidation – loss of electrons
Reduction – gain of electrons
LEO
GER
OIL
RIG
Rules for Assigning Oxidation Numbers
1. Elements in their elemental form are in the zero oxidation state.
2. Group 1 metals are +1 and Group 2 metals are +2.
3. Hydrogen is +1 except when bonded to a metal only (when it’s –1).
4. Transition elements must be determined from anion’s charge
(except Al = +3, Zn = +2, Cd = +2, Ag = +1)
5. The most electronegative elements get their typical oxidation state.
6. The last element not assigned balances the charge of the compound/ion.
Determine the oxidation numbers of all elements in the following:
Cl2
O2
O3
MgCl2
H2O2
N2O4
KO2
NaHCO3
NaN3
CuSO4