2.4 Naming Molecular Compounds

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Video Transcript
In this lesson you will learn:

-The rules for naming molecular compounds


Naming Molecular Compounds

Naming molecular compounds is generally easier than naming ionic compounds.  A molecular compound is composed of two or more nonmetals, and in this lesson you will specifically learn how to name molecular compounds comprised of exactly two nonmetals (known as binary molecular compounds).  There is no worrying about oxidation states and roman numerals as with some ionic compounds.  There is simply a numerical prefix added before the name of each element to indicate how many atoms of that element are in a molecule.  The rules and numerical prefixes are summarized in the tables below.

1. Give the numerical prefix of the first element (omit if only one--mono).
2. Name the first element.
3. Give the numerical prefix for the second element.
4. Name the second element with the -ide suffix.
Naming Molecular Compounds dinitrogen tetroxide
Numerical Prefixes
1 mono
2 di
3 tri
4 tetra
5 penta
6 hexa
7 hepta
8 octa
9 nona
10 deca

Naming Molecular Compounds Examples

Below the names of several binary molecular compounds are summarized.  Note that when there is only one of the 1st element the prefix mono is omitted from the name, but when there is only one of the 2nd element the prefix mono is included.

Chemical Formula 1st Prefix 2nd Prefix
P4O10 tetra phosphorus deca oxide tetraphosphorus decoxide
N2O5 di nitrogen penta oxide dinitrogen pentoxide
SF6 n/a sulfur hexa fluoride sulfur hexafluoride
N2O di nitrogen mono oxide dinitrogen monoxide
CO n/a carbon mono oxide carbon monoxide

Naming Molecular Compounds Practice

Hover over the boxes below to reveal the name/formula.

CO2
carbon dioxide
P2O5
diphosphorus pentoxide
CCl4
carbon tetrachloride
oxygen difluoride
OF2
carbon disulfide
OF2
phosphorus pentachloride
PCl5